Thermal properties of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone.
نویسندگان
چکیده
منابع مشابه
Synergistic Solvent Extraction of Trivalent Lanthanoids with Mixtures of 1-Phenyl-3-methyl-4-benzoyl-5- pyrazolone and Crown Ethers
The synergistic solvent extraction of 14 trivalent lanthanoids (except Pm) with 1-phenyl-3-methyl-4-benzoyl-5pyrazolone(HP) and dibenzo-18-crown-6 (DB18C6) or dibenzo-24-crown-8(DB24C8) in 1, 2-dichloroethane has been studied. It was found that in the presence of HP alone the lanthanoids have been extracted as LnP3∙HP and in the presence of mixtures of HP and crown ethers (S) − as LnP3∙S. On th...
متن کاملStructures of l-Phenyl-3-methyl-pyrazolone-5 and its Benzoyl Derivatives+
The structures of l-phenyl-3-methyl-pyrazolone-5 and its benzoyl derivatives have been investigated by means of IR, UV, NMR, and mass spectral spectroscopy. 1-Phenyl 3-methyl-pyrazolone-5 is found to exist as a zwitter ion in the solid state, in the 5-keto form in chloroform and dioxane, and in the 5-hydroxy form in pyridine. The 4-benzoyl derivative of l-phenyl-3-methyl-pyrazolone-5 is shown t...
متن کاملEffect of Several Auxiliary Ligands on the Extraction of Manganese(II) With 4-Benzoyl-3-methyl-l-phenyl-5-pyrazolone
The effect of 2-methyl pyridine N-oxide, 4-methyl pyridine N-oxide, pyridine N-oxide, 8-aminoquinoline, dibenzyl sulfoxide on the extraction of manganese(II) by 4-benzoyl-3-methyl-1-phe-' nyl-5-pyrazolone (BMPP) in benzene from an aqueous buffered solution was studied. Synergistic enhancement was observed in all systems. Equilibrtum extraction constants and adduct formation constants were calcu...
متن کامل4-[(2-Benzoyl-4-chlorophenyl)diazenyl]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-one
In the title compound, C(23)H(17)ClN(4)O(2), the amino H atom forms an intra-molecular hydrogen bond to the exocyclic carbonyl O atom as well as to the O atom of the benzoyl group.
متن کاملBioassay of 1-phenyl-3-methyl-5-pyrazolone for possible carcinogenicity.
A bioassay of 1-phenyl-3-methyl-5-pyrazolone for possible carcinogenicity was conducted using Fischer 344 rats and B6C3F1 mice. 1-Phenyl-3-methyl-5-pyrazolone was administered in the feed, at either of two concentrations, to groups of 49 or 50 male and 50 female animals of each species. The high and low concentrations of 1-phenyl-3-methyl-5-pyrazolone utilized were, respectively, 5,000 and 2,50...
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ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1995
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.44.25